Raw skin from sunburn and vinegar...?

my face and chest got burnt really badly from the sun. my face is in SO much pain.. its mainly just the left side and especially on my nose. its starting to peel and its really raw.. will putting distilled vinegar on it hurt or help? ive been putting aloe vera lotion and aloe vera gel everywhere but not today since its peeled and been raw.. my chest is just blistered but not in pain until its rubbed the wrong way. my face though.. really bad. i have a gel ice pack in the freezer that im gonna put on it to relieve the sting and im gonna use aloe vera and everything but my question is WILL VINEGAR BURN MY SUNBURN IF ITS ALREADY PEELING? thank youuu in advance!